Monday 8 April 2013

Extraction of Zinc


Extraction of Zinc

 
Ores:Zinc Blende, ZnS
 Calamine, ZnCO3
 Zincite, ZnO
  1. Concentration:
    Powdered Zinc Blende is concentrated by froth floatation process.
     
  2. Roasting:

    2ZnS + 3O2      2ZnO + 2SO2
     
  3. Reduction:

    ZnO + C  Zn + CO
     
  4. Purification:
    Impure Zinc obtained above contain impurities of Pb, Fe, Cd, As etc. This impure Zinc is known as spelter. Firstly, Cd is distilled off at 800C and then electrolytic purification is done using impure Zn as anode and cathode consists of sheets of pure Al. Pure Zn is scrapped off from Al-sheets.

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